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Argentometric titration. Definition: The process of determining the quantity of a sample by adding measured increments of a titrant until the end-point, at which. automatic titrator will be used to perform the titration, and to obtain the titration curve. Background. Argentometric Titrations. In order for a titrimetric method to be . A titration in which Ag+ is the titrant is called an argentometric titration. Table provides a list of several typical precipitation titrations.

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Argentometric (silver nitrate) titrations overview

A comparison of our sketch to the exact titration curve Figure 9. The first type of indicator is a species that forms a precipitate with the titrant. Before precipitation titrimetry became practical, better methods for identifying the end point were necessary.

What are some example of the use of argentometric titration? The third type of end point uses a species that changes color when it adsorbs to the precipitate.

Because CrO 4 2— imparts a yellow color to the solution, which might obscure the end point, only a small amount of K 2 CrO 4 is added. Calcium acetate “fixes” free chlorine, precipitates carbonates, and neutralizes the resultant solution. The stoichiometry of titratilns reaction requires that. All chlorides are dissolved out of the residue, and titrated. For example, after adding Because this equation has two unknowns—g KCl and g NaBr—we need another equation that includes both unknowns.


At the beginning of this section we noted that the first precipitation titration used the cessation of precipitation to signal the end point. Eosin tetrabromofluorescein is suitable for titrating against bromideiodideand thiocyanate anions, giving a sharper end-point than dichlorofluorescein. Calculate the volume of AgNO 3 needed to reach the equivalence titratins.

Home Questions Tags Users Unanswered. This is the same example that we used in developing the calculations for a precipitation titration curve. Before the equivalence point the titrand, Cl —is in excess. In analytical chemistryargentometry is a type of titration involving the silver I ion.

Sign up using Email and Password. A reaction in which the analyte and titrant form an insoluble precipitate also can serve as the basis for a titration. The red arrows show the end points. The concentration of unreacted Cl — after adding By using our site, you acknowledge that you have read and understand our Cookie PolicyPrivacy Titrationand our Terms of Service.

From Wikipedia, the free encyclopedia. In this section we demonstrate a simple method for sketching a precipitation titration curve.

9.5: Precipitation Titrations

A better fit is possible if the two points before the equivalence point argentomeric further apart—for example, 0 mL and 20 mL— and the two points after the equivalence point are further apart. Post Your Answer Discard By clicking “Post Your Answer”, you acknowledge that you have read our updated terms of serviceprivacy policy aryentometric cookie policyand that your continued use of the website is subject to these policies.


Calculate pCl before the equivalence point by determining the concentration of unreacted NaCl. Sign up or log in Sign up using Google. To find the moles of titrant reacting with the sample, we first need to correct for the reagent blank; thus. In the Fajans method, named after Kazimierz Fajanstypically dichlorofluorescein is used as an indicator; the end-point is marked by the green suspension turning pink.

The sample contains 0. Quantitative chemical analysis 6th ed.

A simple equation takes advantage of the fact that the sample contains only KCl and NaBr; thus. Because dichlorofluoroscein also carries a negative charge, it is repelled by the precipitate and remains in solution where it has a greenish-yellow color.

Methods argentomehric on precipitation of silver compounds I are called collectively argentometric methods. The first reagent is added in excess and the second reagent used to back titrate the excess.

Argentometry – Wikipedia

What about argentometric titration? The reaction in this titrahions is. This page was last edited on 5 Decemberat Additional results for the titration curve are shown in Table 9. Calculate pCl at the equivalence point using the K sp for AgCl to calculate the concentration of Cl —.